The Behavior of Olive Stone Powder at High Temperature Steel Corrosion



Abstract Views
358

Downloads
243

Citations

Share

##plugins.themes.bootstrap3.article.sidebar##

Submitted Feb 10, 2018
Published Feb 23, 2018
10.24018/ejeng.2018.3.2.616

Abstract viewed = 358 times

Table of Contents

##plugins.themes.bootstrap3.article.main##

Corrosion of metals is the most significant and difficult life problems, especially its produce an economical losses, therefore, many researches carried out in various fields in order to reduce the bad effect of corrosion, particularly in acidic environments. Using corrosion inhibitors is one of the methods of prevention  corrosion, which come up on organic and inorganic materials, in this study, dried Olive stone powder used as corrosion inhibitor in solutions of hydrochloric acid with concentrations of 0.5, 1 and 1.5 molarity at 40  and 55 , where 10 gm per litter of acid. The corrosion rates of mild steel samples were measured using potentiostat device with reference of calomel electrode. The result shows that corrosion rate reduced by adding the Olive stone powder. The highest inhibition efficiency percent for acid solutions with concentration of 1.5 molarity is 93.8% at 55 , while the lowest was 49.6% in the 0.5 molarity solution at 55 . The chemical composition of the Olive stone powder is shown to be an organic matter of a high carbon and hydrogen content making a carbonyl compound which has the greatest effect in inhibition corrosion in acidic solutions such as hydrochloric acid. 

Keywords: Olive Stone Powder HCl Acid Medium Mild Steel Inhibitor Potentiostat

Downloads

Download data is not yet available.

References

  1. Thompson, N. G., Yunovich, M., & Dunmire, D. "Cost of corrosion and corrosion maintenance strategies," Corrosion Reviews., 25(3-4), 247-262, (2007).
     Google Scholar
  2. Buchweishaija, J. "Phytochemicals as green corrosion inhibitors in various corrosive media: a review." Tanzania Journal of Science, vol 35, no. 1, (2009).
     Google Scholar
  3. Sharma, S.K., Mudhoo, A. and Khamis, E. "Adsorption Studies, Modeling, and Use of Green Inhibitors in Corrosion Inhibition: An Overview of Recent Research," Green Corrosion Chemistry and Engineering: Opportunities and Challenges, pp.319-337, 2008.
     Google Scholar
  4. Patni, N., Agarwal, S. and Shah, P., "Greener approach towards corrosion inhibition," Chinese Journal of Engineering, 2013.
     Google Scholar
  5. Kabanda, M.M. and Ebenso, E.E., "Density functional theory and quantitative structure-activity relationship studies of some quinoxaline derivatives as potential corrosion inhibitors for copper in acidic medium," Int J Electrochem Sci, vol. 7, no. 9, pp.8713-8733, 2012.
     Google Scholar
  6. Kabanda, M.M., Murulana, L.C. and Ebenso, E.E., "Theoretical studies on phenazine and related compounds as corrosion inhibitors for mild steel in sulphuric acid medium," Int J Electrochem Sci, vol. 7, pp.7179-7205, 2012.
     Google Scholar
  7. Devarayan, K., Mayakrishnan, G. and Nagarajan, S. "Green Inhibitors for Corrosion of Metals: A Review", Chemical Science Review and Letters, Vol. 1, no. (1), pp. 1-8, 2012.
     Google Scholar
  8. Control of Environmental Variables in Water-Recirculating Systems, Corrosion, ASM Handbook, ASM International, 1987.
     Google Scholar
  9. Abd El‐Maksoud, S.A., "Electrochemical studies on the effect of pyrazolo‐containing compounds on the corrosion of carbon steel in 1 M sulphuric acid," Materials and Corrosion, vol. 54, no. 2, pp.106-112, 2003.
     Google Scholar
  10. Bentiss F, Bouanis M, Mernari B, Traisnel M, Vezin H, Lagrenee M. "Understanding the adsorption of 4H-1,2,4-triazole derivatives on mild steel surface in molar hydrochloric acid.Appl". Surf. Sci.; vol. 253, pp. 3696 -704, 2007.
     Google Scholar
  11. Ebenso, EE. and Oguzie, EE. "Corrosion inhibition of mild steel in acidic media by some organic dyes,". Mater. Lett. Vol. 59, pp. 2163 -65, 2005.
     Google Scholar
  12. Omotoyinbo, J.A., Oloruntoba, D.T. and Olusegun, S. J. "Corrosion Inhibition of Pulverized Jatropha Curcas Leaves on Medium Carbon Steel in 0.5 M H2SO4 and NaCl Environments", International Journal of Science and Technology, vol. 2, no. 7, pp. 510-514, 2013.
     Google Scholar
  13. Guillermo, R., Antonio, L., Rocıo, R., Ana, J., Rafael, G. and Juan, F., "Olive stone an attractive source of bioactive and valuable compounds" Bioresource Technology, vol. 99, pp. 5261–5269, 2008.
     Google Scholar
  14. Cang, H., Fei, Z.H., Xiao, H.R., Huang, J.L. and Xu, Q., "Inhibition effect of reed leaves extract on steel in hydrochloric acid and sulphuric acid solutions," International Journal of Electrochemical Science, vol. 7, pp.8869-8882, 2012.
     Google Scholar